If you are referring to the Lord of the Rings movies (not the books) and we take into account the extended versions on DVD/BluRay, the counts are as follows:
The Fellowship of the Ring:
Sam killed 3 Orcs by sword, none of the other Hobbits killed any Orcs although Merry and Pippin shared a kill of an Uruk-Hai.
The Two Towers:
Merry and Pippin each killed an Orc by throwing rocks.
The Return of the King:
(this one is trickier as it has the highest overall body count and the character kill breakdowns aren't complete)
Sam kills 4 Orcs, Pippin kills 1-2 Orcs, Merry has 7 listed kills but not specified what race.
Frodo doesn't appear to have killed any throughout the trilogy.
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