"The Christian Old Testament features more than 24 books of the original Hebrew Bible, and deliberately in a divergent order.[11] Moreover, there are a number of different versions of the Christian Bible, with different selections of books, as well as different ordering and naming of books, or incorporation of additional material into the books.
Christian Bibles range from the sixty-six books of the Protestant canon to the eighty-one books of the Ethiopian Orthodox Church canon. The first part of all Christian Bibles is the Old Testament, which contains, at minimum, the twenty-four books of the Hebrew Bible divided into thirty-nine books and ordered differently from the Hebrew Bible. The Catholic Church and Eastern Christian churches also hold certain books and passages that are excluded from the Hebrew Bible to be part of the Old Testament canon.
The second part of the Christian Bible is the New Testament, containing twenty-seven books originally written in Koine Greek, which discuss the teachings and person of Jesus, as well as events in first-century Christianity. The New Testament is divided into the four Canonical gospels, the Acts of the Apostles, twenty-one Epistles or didactic letters, and the Book of Revelation."
https://en.wikipedia.org/wiki/Bible
To calculate the answer based on words depends on the version. Of course, any other translation would differ slightly. Bibles in other languages (such as the Vulgate, in Latin) similarly aren't exactly the same. And then there is the Douay-Rheims translation, commonly (albeit inaccurately) referred to as the Catholic Bible, which includes a number of chapters (all in the Old Testament) which are not included in the Protestant canon, so the Old Testament is correspondingly a larger percentage of that Bible.
http://www.drbo.org/
http://www.latinvulgate.com/
With all those reasons why a precise answer is not possible, the answer will generally be between 70% and 80%.