There is discussion about the pronunciation of 'Czech' on this Wikipedia page,
https://en.wikipedia.org/wiki/Name_of_the_Czech_Republic:-
"The Czech Republic's official formal and short names at the United Nations are ?eská republika and ?esko in Czech, and the Czech Republic and Czechia in English.[1] All these names derive from the name of the Czechs, the West Slavic ethnic group native to the Czech lands. Czechia (/?t??ki?/), the official English short name specified by the Czech government, is used by many international organisations and attested as early as 1841. However, most English speakers use [the] Czech Republic in all contexts.[2][3] Other languages generally have greater official use of a short form analogous to ?esko or Czechia[4][5] (such as French [la] Tchéquie, or Russian ?????/Chekhiya, or Korean ???/Ches?kko or ??/Chekho) although forms equivalent to "Czech Republic" are not uncommon."
This Wikipedia page
https://en.wikipedia.org/wiki/Tsar gives the Cyrillic spelling of 'tsar' or 'czar'.
"The title tsar (Cyrillic: ????) is derived from the Latin title for the Roman emperors, caesar."
The last sentence I've copied about 'Czech' gives the Russian spelling - '?????'. It starts with a different letter from '????'. As I learnt them at school, '?' sounds like 'ch' in 'cheese', and '?' sounds like 'ts' in 'spots'.
Oh dear - all the Cyrillic characters don't seem to show on this page. You should be able to see them on the Wikipedia pages.
Here is a link to a Cyrillic keyboard where you can see the two characters in eighth and ninth places in the middle of the bottom row. The eighth one has the 'ts' sound, and the ninth the 'ch' sound.
https://www.lexilogos.com/keyboard/russian.htm